{"ATC Code":"R05DA09","Abbreviation":"DXM","Aliases":["methorphan","Methorphan","Δ-Methorphan","morphan","methorfan","metorfano","methorphane","Albutussin","Destrometerfano","methorphanum","BA 2666","Balminil DM","Nodex","3-Methoxy-17-methyl-9α,13α,14α-morphinan","Morphinan, 3-methoxy-17-methyl-, (9α,13α,14α)-","Calmylin","DXM","3-Methoxy-N-methylmorphinon","BA-2666","9α,13α,14α-Morphinan, 3-methoxy-17-methyl-","3-methoxy-n-methylmorphinan","4-21-00-01367","9-α,13-α,14-α-Morphinan, 3-methoxy-17-methyl-","Morphinan, 3-methoxy-17-methyl-, (9-α,13-α,14-α)-","cis-1,3,4,9,10,10a-Hexahydro-6-methoxy-11-methyl-2H-10,4α-iminoethanophenanthren"],"Biological Half-Life":"Dextromethorphan has a half life of 3-30 hours.","CAS":"125-71-3","ChEBI":"CHEBI:4470","ChEMBL":"CHEMBL52440","ChemicalClasses":["morphinan"],"Chirality":"absolute","Color/Form":"White to slightly yellow crystalline powder","Decomposition":"When heated to decomposition it emits toxic fumes of /nitrogen oxides/.","Drug Classes":"Breast Feeding; Lactation; Milk, Human; Antitussive Agents","Drug Indication":"Dextromethorphan is indicated in combination with [brompheniramine] and [pseudoephedrine] in the treatment of coughs and upper respiratory symptoms associated with allergies or the common cold. Dextromethorphan is also used in combination with [guaifenesin] as an over-the-counter product to relieve a cough. Dextromethorphan in combination with [quinidine] is indicated in the treatment of pseudobulbar affect.","Drug Warnings":"Administration of dextromethorphan may be associated with histamine release, and the drug should be used with caution in atopic children. Dextromethorphan also should be used with caution in sedated or debilitated patients and in patients confined to the supine position. Dextromethorphan should not be taken for persistent or chronic cough (e.g., with smoking, emphysema, asthma) or when coughing is accompanied by excessive secretions, unless directed by a clinician. If cough persists for longer than 1 week, tends to recur, or is accompanied by high fever, rash, or persistent headache, a clinician should be consulted.","DurationOfAction":"3 – 8 hours","EINECS":"204-752-2","EliminationHalfLife":"2 – 4 hours (extensive metabolizers); 24 hours (poor metabolizers)\u003ca href='#cite_note-3'\u003e\u003csup\u003e[3]\u003c/sup\u003e\u003c/a\u003e","Esters":[],"European Community (EC) Number":"204-752-2","FDA Pharmacological Classification":"7355X3ROTS","Formating":[],"HeavyAtomCount":20,"Human Drugs":"Breast Feeding; Lactation; Milk, Human; Antitussive Agents","IUPACName":"(1S,9S,10S)-4-methoxy-17-methyl-17-azatetracyclo[7.5.3.01,10.02,7]heptadeca-2(7),3,5-triene","InChI":"InChI=1S/C18H25NO/c1-19-10-9-18-8-4-3-5-15(18)17(19)11-13-6-7-14(20-2)12-16(13)18/h6-7,12,15,17H,3-5,8-11H2,1-2H3/t15-,17+,18+/m1/s1","InChIKey":"MKXZASYAUGDDCJ-NJAFHUGGSA-N","MeSH Pharmacological Classification":"Agents that suppress cough. They act centrally on the medullary cough center. EXPECTORANTS, also used in the treatment of cough, act locally. (See all compounds classified as Antitussive Agents.)","Melting Point":"122-124","MolecularFormula":"C\u003csub\u003e18\u003c/sub\u003eH\u003csub\u003e25\u003c/sub\u003eNO","MolecularWeight":"271.4 g/mol","Odor":"Odorless","Opticalactivity":"( + )","Pharmacodynamics":"Dextromethorphan is an opioid-like molecule indicated in combination with other medication in the treatment of coughs and pseudobulbar affect. It has a moderate therapeutic window, as intoxication can occur at higher doses. Dextromethorphan has a moderate duration of action. Patients should be counselled regarding the risk of intoxication.","PubChemId":5360696,"RefCount":4,"RefCur":"","References":[{"Name":"Wikipedia","Urls":[{"Link":"https://en.wikipedia.org/wiki/Dextromethorphan","Name":"Dextromethorphan","Sub":false}]},{"Name":"Wikidata","Urls":[{"Link":"https://www.wikidata.org/wiki/Q407781","Name":"Dextromethorphan","Sub":false}]},{"Name":"DrugBank","Urls":[{"Link":"https://go.drugbank.com/drugs/DB00514","Name":"Dextromethorphan","Sub":false}]},{"Name":"PubChem","Urls":[{"Link":"https://pubchem.ncbi.nlm.nih.gov/compound/5360696","Name":"Dextromethorphan","Sub":false}]},{"Name":"ChEMBL","Urls":[{"Link":"https://www.ebi.ac.uk/chembl/explore/compound/CHEMBL52440","Name":"Dextromethorphan","Sub":false}]},{"Name":"ChEBI","Urls":[{"Link":"https://www.ebi.ac.uk/chebi/searchId.do?chebiId=CHEBI:4470","Name":"Dextromethorphan","Sub":false}]},{"Name":"Common Chemistry","Urls":[{"Link":"https://commonchemistry.cas.org/detail?cas_rn=125-71-3","Name":"Dextromethorphan","Sub":false}]},{"Name":"KEGG","Urls":[{"Link":"https://www.kegg.jp/entry/C06947","Name":"Dextromethorphan","Sub":false}]},{"Name":"UNII","Urls":[{"Link":"https://gsrs.ncats.nih.gov/ginas/app/ui/substances/7355X3ROTS","Name":"Dextromethorphan","Sub":false}]},{"Name":"EPA DSSTox","Urls":[{"Link":"https://comptox.epa.gov/dashboard/chemical/details/DTXSID3022908","Name":"Dextromethorphan","Sub":false}]}],"Refs":["National Center for Biotechnology Information. PubChem Compound Summary for CID 5360696, methorphan. Accessed July 7, 2025. \u003ca href=https://pubchem.ncbi.nlm.nih.gov/compound/5360696\u003ehttps://pubchem.ncbi.nlm.nih.gov/compound/5360696\u003c/a\u003e","U.S. Food and Drug Administration; National Center for Advancing Translational Sciences. methorphan. UNII: 7355X3ROTS. Global Substance Registration System. Accessed July 7, 2025. \u003ca href=https://gsrs.ncats.nih.gov/ginas/app/beta/substances/7355X3ROTS\u003ehttps://gsrs.ncats.nih.gov/ginas/app/beta/substances/7355X3ROTS\u003c/a\u003e","Balminil DM, Benylin DM (dextromethorphan) dosing, indications, interactions, adverse effects, and more. WebMD. Accessed July 7, 2025. \u003ca href=http://reference.medscape.com/drug/balminil-dm-benylin-dm-dextromethorphan-343401#showall\u003ehttp://reference.medscape.com/drug/balminil-dm-benylin-dm-dextromethorphan-343401#showall\u003c/a\u003e"],"SMILES":"CN1CC[C@@]23CCCC[C@@H]2[C@@H]1CC4=C3C=C(C=C4)OC","SaltData":[{"AcidCount":1,"AmineCount":1,"Formula":"I","Name":"hydriodide","Structure":"\u003csvg  preserveAspectRatio=\"none\" style=\"display:block\" viewBox=\"0 0 95.377 93.34\"\u003e\u003crect width=\"100%\" height=\"100%\" fill=\"#fff\"/\u003e\u003cdesc\u003eGenerated by the Chemistry Development Kit (http://github.com/cdk)\u003c/desc\u003e\u003cg stroke=\"#000\" stroke-linecap=\"round\" stroke-linejoin=\"round\" stroke-width=\".7\"\u003e\u003cpath fill=\"#fff\" stroke=\"none\" d=\"M0 0h96v94H0z\"/\u003e\u003cg class=\"mol\"\u003e\u003cpath d=\"m74.783 83.466-4.378-10.274M68.863 65.604l.152-11.381\" class=\"bond\"/\u003e\u003cpath stroke=\"none\" d=\"M42.311 54.62c-.136 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class=\"hi\"/\u003e\u003c/g\u003e\u003cg class=\"mol\"\u003e\u003cg fill=\"#1ff01f\" stroke=\"none\" class=\"atom\"\u003e\u003cpath d=\"M95.394 44.818q-.785 0-1.238.53-.452.524-.452 1.447 0 .911.416 1.446.423.53 1.268.53.322 0 .608-.053.291-.06.565-.143v.536q-.274.101-.565.148-.292.054-.697.054-.744 0-1.25-.31-.5-.309-.75-.875-.25-.571-.25-1.339 0-.744.268-1.31.274-.565.803-.881.53-.321 1.28-.321.78 0 1.352.285l-.244.524q-.227-.101-.506-.184-.274-.084-.608-.084m2.757 4.424h-.601v-5.215h.601zM92.487 49.242h-.619v-2.286h-2.512v2.286h-.613v-4.9h.613v2.072h2.512v-2.072h.619z\"/\u003e\u003c/g\u003e\u003c/g\u003e\u003c/g\u003e\u003c/svg\u003e","Title":"Dextromethorphan hydrochloride","UNII":"351KFH969D"},{"AcidCount":1,"AmineCount":1,"Formula":"Br","Name":"hydrobromide","Structure":"\u003csvg  preserveAspectRatio=\"none\" style=\"display:block\" viewBox=\"0 0 100.126 93.34\"\u003e\u003crect width=\"100%\" height=\"100%\" fill=\"#fff\"/\u003e\u003cdesc\u003eGenerated by the Chemistry 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stroke=\"#ff0d0d\" d=\"m6.095 18.033 4.957 2.864M2.82 12.22l.001-5.655\" class=\"hi\"/\u003e\u003c/g\u003e\u003cg class=\"mol\"\u003e\u003cg fill=\"#a62929\" stroke=\"none\" class=\"atom\"\u003e\u003cpath d=\"M94.448 44.22q.917 0 1.387.274.47.268.47.941 0 .434-.244.72-.238.286-.69.363v.036q.309.047.559.178t.393.375q.149.238.149.619 0 .667-.458 1.03-.459.364-1.245.364h-1.72v-4.9zm.119 2.09q.631 0 .863-.203.238-.202.238-.601 0-.405-.285-.577-.286-.179-.911-.179h-.81v1.56zm-.905.512v1.774h.988q.655 0 .905-.25.256-.256.256-.667 0-.381-.268-.619-.262-.238-.94-.238zm5.476-1.447q.101 0 .22.012.125.006.208.03l-.071.553q-.089-.018-.197-.029-.107-.018-.202-.018-.28 0-.53.154-.244.155-.393.435-.149.274-.149.649v1.959h-.601v-3.674h.494l.066.667h.03q.178-.297.458-.518.28-.22.667-.22M92.487 49.12h-.619v-2.286h-2.512v2.286h-.613v-4.9h.613v2.072h2.512V44.22h.619z\"/\u003e\u003c/g\u003e\u003c/g\u003e\u003c/g\u003e\u003c/svg\u003e","UNII":"9D2RTI9KYH"}],"Salts":["hydriodide","salicylate","hydrobromide","hydrochloride"],"Scheduling":[{"gov":"Australia","ref":[],"schedule":"S2 substance"},{"gov":"United Kingdom","ref":[],"schedule":"P substance"},{"gov":"United States","ref":[],"schedule":"OTC substance"},{"gov":"Canada","ref":[],"schedule":"OTC substance"},{"gov":"United Nations","ref":[],"schedule":"Unscheduled substance"}],"Solubility":"Practically insoluble in water","Stability/Shelf Life":"Stable under recommended storage conditions. /Dextromethorphan hydrobromide/","StereoisomerData":[{"Aliases":["dextromethorphan","d-Methorphan","Δ-Methorphan","Dextromorphan","Dextromethorfan","Dextrometorfano","Dextromethorphane","Albutussin","Destrometerfano","Dextromethorphanum","BA 2666","Balminil DM","Nodex","3-Methoxy-17-methyl-9α,13α,14α-morphinan","Morphinan, 3-methoxy-17-methyl-, (9α,13α,14α)-","Calmylin","Dextromethorphan","DXM","(+)-3-Methoxy-N-methylmorphinon","BA-2666","9α,13α,14α-Morphinan, 3-methoxy-17-methyl-","(+)-3-methoxy-n-methylmorphinan","4-21-00-01367","9-α,13-α,14-α-Morphinan, 3-methoxy-17-methyl-","Morphinan, 3-methoxy-17-methyl-, (9-α,13-α,14-α)-"],"PubChemId":5360696,"SMILES":"CN1CC[C@@]23CCCC[C@@H]2[C@@H]1CC4=C3C=C(C=C4)OC","Structure":"\u003csvg  preserveAspectRatio=\"none\" style=\"display:block\" viewBox=\"0 0 75.803 93.34\"\u003e\u003crect width=\"100%\" height=\"100%\" fill=\"#fff\"/\u003e\u003cdesc\u003eGenerated by the Chemistry Development Kit (http://github.com/cdk)\u003c/desc\u003e\u003cg stroke=\"#000\" stroke-linecap=\"round\" stroke-linejoin=\"round\" stroke-width=\".7\"\u003e\u003cpath fill=\"#fff\" stroke=\"none\" d=\"M0 0h76v94H0z\"/\u003e\u003cg class=\"mol\"\u003e\u003cpath d=\"m74.783 83.466-4.378-10.274M68.863 65.604l.152-11.381\" class=\"bond\"/\u003e\u003cpath stroke=\"none\" d=\"M42.311 54.62c-.136 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